Chemical Warfare Service 10 M ......Airplane Smoke s/n 3561 EMSCO LOT
C-59-1 S.C.1
Chemicals
used for smoke generation and other applications
Sulfur Mustard ( Mustard gas )
Mustard gas was
first used effectively in World War I by the German army against British soldiers near Ypres, Belgium, in 1917 and later also
against the French Second Army. The name Yperite comes from its usage by the German army near the town of Ypres. The
Allies did not use mustard gas until November 1917 at Cambrai, France, after the armies had captured a stockpile of German
mustard-gas shells. It took the British more than a year to develop their own mustard gas weapon. (The only option available
to the British was the Despretz–Niemann–Guthrie process). This was used first in September 1918 during the breaking
of the Hindenburg Line.
Mustard gas was
dispersed as an aerosol in a mixture with other chemicals, giving it a yellow-brown color and a distinctive odor. Mustard
gas has also been dispersed in such munitions as aerial bombs, land mines, mortar rounds, artillery shells, and rockets.
Exposure to mustard gas was lethal in about one percent of cases. Its effectiveness was as an incapacitating agent.
The early countermeasures against mustard gas were relatively ineffective, since a soldier wearing a gas mask was not protected
against absorbing it through his skin and being blistered.
Mustard gas is
a persistent weapon that remains on the ground for days and weeks, and it continues to cause ill effects. If mustard gas contaminates
a soldier's clothing and equipment, then the other soldiers that he comes into contact with are also poisoned. Towards the
end of World War I, mustard gas was used in high concentrations as an area-denial weapon that forced troops to abandon heavily-contaminated
areas.
Since
World War I, mustard gas has been used in several wars or other conflicts, usually against people who cannot retaliate:
- United Kingdom
against the Red Army in 1919
- Spain
and France against Rif insurgents in Morocco during 1921 – 27
- Italy
in Libya during 1930
- The Soviet Union
in Xinjiang, Republic of China, during the Soviet Invasion of Xinjiang against the 36th Division (National Revolutionary Army)
in 1934, and also in the Xinjiang War (1937) during 1936 – 37
- Italy against
Abyssinia (now Ethiopia) from 1935 to 1940
- Nazi Germany
against Poland and the Soviet Union in a few incidents during World War II
- Poland against
Germany in 1939 during an isolated incident, using a British product
- The Japanese
Empire against China during 1937 – 45
- Egypt against
North Yemen during 1963 – 67
- Iraq against
Iran and the Kurds during 1983 – 88
- Possibly Sudan
against insurgents in the civil war, in 1995 and 1997
In 1943, during
the Second World War, an American shipment of mustard gas exploded aboard a supply ship that was bombed during
an air raid in the harbor of Bari, Italy. Eighty-three of the 628 hospitalized victims who had been exposed to the mustard
gas died. The deaths and incident were partially classified for many years.
Zinc chloride
Zinc chloride
smoke is grey-white and consists of tiny particles of zinc chloride. The most common mixture for generating these is the zinc chloride smoke mixture (HC), consisting of hexachloroethane,
grained aluminium and zinc oxide. The smoke consists of zinc chloride, zinc oxychlorides, and hydrochloric acid, which absorb
the moisture in the air. The smoke also contains traces of organic chlorinated compounds, phosgene, carbon monoxide, and chlorine.
Its toxicity
is caused mainly by the content of strongly acidic hydrochloric acid, but also due to thermal effects of reaction of zinc
chloride with water. These effects cause lesions of the mucous membranes of the upper airways. Damage of the lower airways
can manifest itself later as well, due to fine particles of zinc chloride and traces of phosgene. In high concentrations the
smoke can be very dangerous when inhaled. Symptoms include dyspnea, retrosternal pain, hoarseness, stridor, lachrymation,
cough, expectoration, and in some cases haemoptysis. Delayed pulmonary edema, cyanosis or bronchopneumonia may develop. The
smoke and the spent canisters contain suspected carcinogens.
The prognosis for the casualties depends on the degree of the pulmonary
damage. All exposed individuals should be kept under observation for 8 hours. Most affected individuals recover within several
days, with some symptoms persisting for up to 1–2 weeks. Severe cases can suffer of reduced pulmonary function for some
months, the worst cases developing marked dyspnea and cyanosis leading to death.
Respirators are required for people coming into contact with the zinc
chloride smoke.
Chlorosulfuric
acid
Chlorosulfuric
acid (CSA) is a heavy, strongly acidic liquid. When dispensed in air, it readily absorbs moisture and forms dense white
fog of hydrochloric acid and sulfuric acid. In moderate concentrations it is highly irritating to eyes, nose, and skin.
When chlorosulfuric
acid comes in contact with water, a strong exothermic reaction scatters the corrosive mixture in all directions. CSA is highly
corrosive, so careful handling is required.
Low concentrations
cause prickling sensations on the skin, but high concentrations or prolonged exposure to field concentrations can cause severe
irritation of the eyes, skin, and respiratory tract, and mild cough and moderate contact dermatitis can result. Liquid CSA
causes acid burns of skin and exposure of eyes can lead to severe eye damage.
Affected body
parts should be washed with water and then with sodium bicarbonate solution. The burns are then treated like thermal burns.
The skin burns heal readily, while cornea burns can result in residual scarring.
Respirators are required for any concentrations sufficient to cause
any coughing, irritation of the eyes or prickling of the skin.
Titanium
tetrachloride
Titanium tetrachloride
(FM) is a yellow, non-flammable, corrosive liquid. In contact with damp air it hydrolyzes readily, resulting in a dense
white smoke consisting of droplets of hydrochloric acid and particles of titanium oxychloride.
The titanium tetrachloride smoke is irritant and unpleasant to breathe.
It is dispensed from aircraft to create vertical smoke curtains, and
during World War II it was a favorite smoke generation agent on warships.
Goggles or a respirator should be worn when in contact with the smoke,
full protective clothing should be worn when handling liquid FM. In direct contact with skin or eyes, liquid FM causes acid
burns.
Phosphorus
White phosphorus (weapon)
Red phosphorus and
white phosphorus
(WP) are red or waxy yellow or white substances. White phosphorus is pyrophoric - can be handled safely when under water, but in contact with air it spontaneously
ignites. It is used as an incendiary. Both types of phosphorus are used for smoke generation, mostly in artillery shells,
bombs, and grenades.
White phosphorus smoke is typically very hot and may cause burns on
contact. Red phosphorus is less reactive, does not ignite spontaneously, and its smoke does not cause thermal burns - for
this reason it is safer to handle, but cannot be used so easily as an incendiary.
Aerosol of burning
phosphorus particles is an effective obscurant against thermal imaging systems. However, this effect is short-lived. After
the phosphorus particles fully burn, the smoke reverts from emission to absorption. While very effective in the visible spectrum,
cool phosphorus smoke has only low absorption and scattering in infrared wavelengths. Additives in the smoke that involve
this part of the spectrum may be visible to thermal imagers or IR viewers.
Dyes
Colored smoke
Various signalling
purposes require the use of colored smoke. The smoke created is a fine mist of dye particles, generated by burning a mixture
of one or more dyes with a low-temperature pyrotechnic composition, usually based on potassium chlorate and lactose (also
known as milk sugar).
Colored smoke screen is also possible by adding a colored dye into
the fog oil mixture. Typical white smoke screen uses titanium dioxide (or other white pigment), but other colors are possible
by replacing titanium dioxide with another pigment. When the hot fog oil condenses on contact with air, the pigment particles
are suspended along with the oil vapor. Early smoke screen experiments attempted the use of colored pigment, but found that
titanium dioxide was the most light scattering particle known and therefore best for use in obscuring troops and naval vessels.
Colored smoke became primarily used for signaling rather than obscuring. In today's military, smoke grenades are found to
be non-cancer causing, unlike the 50's AN-M8 model.